Surreal illustration of stainless steel decaying under intense heat.

The Silent Thief: How Aging Impacts Stainless Steel and What You Can Do

"Uncover the hidden effects of short-term aging on lean duplex stainless steel and discover strategies to protect your investments."


Stainless steel is known for its strength and resistance to corrosion, making it essential in industries ranging from oil refining to pharmaceuticals. Duplex stainless steels, in particular, offer an enhanced combination of strength and corrosion resistance compared to standard austenitic stainless steels. Lean duplex stainless steels (LDSSs) offer a cost-effective alternative without sacrificing significant performance, balancing affordability with the necessary durability for various applications.

However, even the toughest materials have their vulnerabilities. Exposing lean duplex stainless steel to temperatures between 400 and 1000 °C during manufacturing or welding can cause significant changes in its structure. This process, known as short-time aging, can lead to the formation of unwanted phases that compromise the material's integrity. Understanding these changes is crucial for maintaining the reliability and safety of equipment and structures built with LDSS.

This article explores how short-time aging impacts the pitting corrosion behavior and mechanical properties of a novel lean duplex stainless steel (LDSS) 2002. By understanding the underlying mechanisms and potential consequences, you can take proactive steps to protect your investments and ensure long-term performance.

What Happens When Stainless Steel Ages?

Surreal illustration of stainless steel decaying under intense heat.

When LDSS 2002 is exposed to high temperatures, it undergoes microstructural changes that affect its resistance to pitting corrosion and its mechanical strength. The main culprits are the formation of secondary phases, such as Cr2N and M23C6, which precipitate along the ferrite-austenite grain boundaries. These precipitates deplete chromium from the surrounding areas, making the steel more susceptible to corrosion and reducing its toughness.

To understand the effects of aging, researchers conducted potentiostatic critical pitting temperature (CPT) tests and Charpy impact tests on LDSS 2002 samples aged at different temperatures. The results revealed a significant degradation in both pitting corrosion resistance and toughness, particularly at 650 °C. At this temperature, the CPT decreased by 28 °C, and the impact energy dropped dramatically from 69 to 29 J/cm² compared to the solution-annealed sample.
Here’s a quick look at the key changes observed during aging:
  • Formation of Secondary Phases: Precipitation of Cr2N and M23C6 along grain boundaries.
  • Chromium Depletion: Reduced chromium concentration in areas surrounding precipitates.
  • Decreased CPT: Lower resistance to pitting corrosion.
  • Reduced Impact Energy: Lower toughness and increased brittleness.
The most significant reduction in CPT and impact energy occurred concurrently at 650 °C, highlighting the critical impact of this temperature range on the material's properties. Transmission electron microscopy (TEM) confirmed that the main precipitates formed at this temperature were Cr2N and M23C6, which accumulated along the ferrite-austenite grain boundaries.

Protecting Your Stainless Steel Investments: Practical Steps

Understanding how short-time aging affects LDSS 2002 is the first step in mitigating its impact. While the changes at a microstructural level may seem daunting, several practical strategies can help maintain the integrity and extend the lifespan of your stainless steel components. By implementing careful heat treatment protocols, controlling the welding environment, and choosing appropriate operating temperatures, you can minimize the risks associated with aging and ensure the continued reliability of your materials.

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