Microscopic mineral inclusions inside a diamond.

Hidden Worlds Within Diamonds: How Tiny Inclusions Reveal Earth's Secrets

"Unlocking the mysteries of diamond formation through the study of nanometer-sized olivine inclusions and their preferred orientations."


Diamonds, prized for their beauty and durability, also serve as time capsules, preserving tiny inclusions that offer invaluable insights into Earth's deep mantle. These inclusions, often composed of minerals and fluids, provide a snapshot of the extreme conditions under which diamonds crystallize. The study of these inclusions has become a cornerstone of modern geology, helping scientists unravel the complexities of our planet’s history.

One particularly intriguing aspect is the orientation of minerals within these inclusions. Do these minerals align randomly, or do they exhibit preferred crystallographic orientations? Understanding these orientations can shed light on the formation processes and the environmental factors at play during diamond genesis. Recent research has focused on nanometer-sized inclusions, pushing the boundaries of analytical techniques and revealing previously unseen details.

This article delves into a groundbreaking study that examines the orientation of olivine, a common mineral, within nanometer-sized fluid inclusions found in Aykhal diamonds. By employing advanced transmission electron microscopy (TEM), researchers have uncovered fascinating patterns in olivine orientations, challenging existing theories and opening new avenues for understanding diamond formation and the Earth's deep carbon cycle.

What Can Olivine Inclusions Tell Us About Diamond Formation?

Microscopic mineral inclusions inside a diamond.

The study focuses on Aykhal diamonds, known for their unique geological context within the Siberian craton. Researchers analyzed healed internal cleavages—essentially tiny fractures—at the core of diamond samples. These cleavages are decorated with ultrapotassic fluid/melt inclusion pockets, containing nanosized graphite, phlogopite, and olivine. The research team found that olivine inclusions are either rounded, surrounded by ample fluid, or facetted, molded by the diamond's {111} faces with only a thin film of fluid between them.

Transmission electron microscopy revealed two distinct crystallographic characteristics of the olivine inclusions:

  • Pronounced crystallographic texture: Olivines grouped within specific diamond domains exhibit similar orientations.
  • Frequent parallelism: Specific low-energy faces of olivine and the surrounding diamond tend to align, indicating preferred crystallographic relationships.
The most common alignments observed were between (010)ol, {120}ol, (001)ol, and specific faces of the diamond, including {111}dia, {110}dia, and {100}dia, in descending order of preference. These alignments form low-energy phase boundaries with a thin liquid film of just 1-2 nanometers separating the minerals. This suggests extremely low adhesion energies between olivine and diamond, facilitating these specific orientations.

Implications and Future Directions

These findings have significant implications for our understanding of diamond formation. The study demonstrates that the crystallographic orientations of olivine inclusions in diamond are not random but are influenced by interfacial energetics and the presence of a fluid phase. This control allows olivine crystals precipitating from parental fluids to settle and attach to low-energy facets on the diamond surface, resulting in distinct, non-random orientations. The results challenge traditional topotaxy or epitaxy concepts observed in oxide/silicate mineral pairs and suggest a process more akin to Van der Waals heteroepitaxy in artificial systems. Future research should explore the variability of these orientations across different diamond types and geological settings to refine our models of diamond genesis and the Earth's deep carbon cycle.

About this Article -

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This article is based on research published under:

DOI-LINK: 10.1016/j.lithos.2018.10.026, Alternate LINK

Title: Low-Energy Phase Boundary Pairs And Preferred Crystallographic Orientations Of Olivines In Nanometer-Sized Ultrapotassic Fluid Inclusions Of Aykhal Diamond

Subject: Geochemistry and Petrology

Journal: Lithos

Publisher: Elsevier BV

Authors: S.L. Hwang, P. Shen, T.F. Yui, H.T. Chu, A.M. Logvinova, N.V. Sobolev

Published: 2018-12-01

Everything You Need To Know

1

What do diamond inclusions tell us about Earth's deep mantle?

Diamonds contain tiny inclusions of minerals and fluids that act as time capsules, providing snapshots of the extreme conditions under which diamonds crystallize deep within the Earth's mantle. The study of these inclusions, such as olivine, graphite, and phlogopite, has become a crucial aspect of modern geology, allowing scientists to understand the complex history of our planet. These inclusions preserve materials from the environment where the diamond formed, giving us clues about the chemical and physical conditions present at great depths.

2

What methods were used to study the Olivine in the Aykhal diamonds?

Researchers analyzed Aykhal diamonds, focusing on healed internal cleavages—tiny fractures—at the core of diamond samples. These cleavages are decorated with ultrapotassic fluid/melt inclusion pockets, containing nanosized graphite, phlogopite, and olivine. Transmission electron microscopy (TEM) revealed distinct crystallographic characteristics of the olivine inclusions. They found that olivine inclusions exhibit specific alignments with the surrounding diamond, suggesting that interfacial energetics and the presence of a fluid phase play a significant role in determining these orientations.

3

What determines the preferred crystallographic orientations of olivine inclusions within diamonds?

The preferred crystallographic orientations of olivine inclusions within diamonds are influenced by interfacial energetics and the presence of a fluid phase. The most common alignments observed were between (010)ol, {120}ol, (001)ol, and specific faces of the diamond, including {111}dia, {110}dia, and {100}dia, in descending order of preference. This allows olivine crystals precipitating from parental fluids to settle and attach to low-energy facets on the diamond surface, resulting in distinct, non-random orientations.

4

How do the orientations of olivine inclusions challenge traditional concepts of mineral alignment?

The non-random orientations of olivine inclusions challenge traditional topotaxy or epitaxy concepts typically observed in oxide/silicate mineral pairs. Instead, the process is more akin to Van der Waals heteroepitaxy, which is commonly found in artificial systems. This suggests that the interactions between olivine and diamond are governed by weak forces and interfacial energies, leading to specific alignments that minimize energy. Understanding these interactions provides new insights into how minerals crystallize together under extreme conditions.

5

What further research is needed to advance our understanding of diamond formation and the Earth's deep carbon cycle?

Further research is needed to explore the variability of olivine orientations across different diamond types and geological settings. This will help refine models of diamond genesis and improve our understanding of the Earth's deep carbon cycle. Additionally, investigating other types of inclusions and their orientations can provide a more comprehensive picture of the conditions and processes occurring deep within the Earth's mantle. Such studies will also allow understanding of other diamonds and their differences.

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